Publication of Department of Chemistry annual year 2015-16

Department of Chemistry

Book Chapters

(1) Kaur N., Bhardwaj V.K., and Singh N., “Surface Decoration of Organic Ligands on Quantum Dots: Fine Tuning of Photophysical Properties” Handbook of Nanoparticles, pp. 1-20, Springer, 2015.

Journals

(1) A. Singh, T. Raj, and N. Singh, “Highly selective and efficient reduction of nitroarenes by imidazolium salt stabilized copper nanoparticles in aqueous medium,” Catal. Letters, vol. 145, no. 8, pp. 1606–1611, 2015.

 

(2) A. Singh, J. Singh, N. Singh, and D. O. Jang, “A benzimidazolium-based mixed organic–inorganic polymer of Cu(II) ions for highly selective sensing of phosphates in water: applications for detection of harmful organophosphates,” Tetrahedron, vol. 71, no. 36, pp. 6143–6147, 2015.

 

(3) A. Saini, A. K. K. Bhasin, N. Singh, and N. Kaur, “Development of a Cr(III) ion selective fluorescence probe using organic nanoparticles and its real time applicability,” New J. Chem., vol. 40, no. 1, pp. 278–284, 2016.

 

(4) A. Huerta Carlos, T. Pandiyan, J. Arenas-Alatorre, and N. Singh, “Oxidation of phenols by TiO2- Fe3O4-M (M=Ag or Au) hybrid composites under visible light,” Sep. Purif. Technol., vol. 149, pp. 265–278, 2015.

 

(5) A. Ghosh, A. K. Pandey, and P. Banerjee, “Lewis Acid Catalyzed Annulation of Donor-Acceptor Cyclopropane and N-Tosyl aziridine dicarboxylate: One-Step Synthesis of Functionalized 2HFuro[2,3-c]pyrroles,” J. Org. Chem., vol. 80, no. 14, pp. 7235–7242, 2015.

 

(6) A. Joshi, W. Schuhmann, and T. C. Nagaiah, “Mesoporous nitrogen containing carbon materials for the simultaneous detection of ascorbic acid, dopamine and uric acid,” Sensors Actuators, B Chem., vol. 230, pp. 544–555, 2016.

 

(7) A. Joshi and T. C. Nagaiah, “Nitrogen-doped carbon nanotubes for sensitive and selective determination of heavy metals,” RSC Adv., vol. 5, no. 127, pp. 105119–105127, 2015.

 

(8) A. Tiwari, T. C. Nagaiah, "Mesoporous Nitrogen-Rich Carbon as Metal-free Anode Catalyst for Borohydride Fuel Cells," Energy Technology, vol. 4, no.4.pp. 479-483,2016.

 

(9) A. Kumari, B. Kaur, R. Srivastava, and R. S. Sangwan, “Isolation and immobilization of alkaline protease on mesoporous silica and mesoporous ZSM-5 zeolite materials for improved catalytic properties,” Biochem. Biophys. Reports, vol. 2, pp. 108–114, 2015.

 

(10) A. Kaur, G. Kaur, A. Singh, N. Singh, and N. Kaur, “Polyamine Based Ratiometric Fluorescent Chemosensor for Strontium Metal Ion in Aqueous Medium: Application in Tap Water, River Water, and in Oral Care,” 2015.

 

(11) A. Tiwari, T.C. Nagaiah, A. Bordoloi, “Electrocatalytic Activity of Tungsten Oxide Nanoclusters Grafted on Mesoporous Nitrogen-Rich Carbon Material in the Dioxygen Reduction Reaction,” ChemPlusChem, vol. 80, pp. 1666–1672, 2015.

 

(12) A. Saini, N. Kaur, and N. Singh, “A highly fluorescent sensor based on hybrid nanoparticles for selective determination of furosemide in aqueous medium,” Sensors Actuators, B Chem., vol. 228, pp. 221–230, 2016.

 

(13) A. Kaur, T. Raj, S. Kaur, N. Singh, and N. Kaur, “Fluorescent organic nanoparticles of  dihydropyrimidone derivatives for selective recognition of iodide using a displacement assay: application of the sensors in water and biological fluids,” Org. Biomol. Chem., vol. 13, no. 4, pp. 1204–1212, 2015.

 

(14) B. Kaur, R. Srivastava, and B. Satpati, “Highly Efficient CeO2 Decorated Nano-ZSM-5 Catalyst for Electrochemical Oxidation of Methanol,” ACS Catal., vol. 6, no. 4, pp. 2654–2663, 2016.

 

(15) B. Kaur, R. Srivastava, and B. Satpati, “Copper nanoparticles decorated polyaniline–zeolite nanocomposite for the nanomolar simultaneous detection of hydrazine and phenylhydrazine,” Catal. Sci. Technol., vol. 6, no. October, pp. 1134–1145, 2016.

 

(16) B. Kaur, R. Srivastava, B. Satpati, K. K. Kondepudi, and M. Bishnoi, “Biomineralization of hydroxyapatite in silver ion-exchanged nanocrystalline ZSM-5 zeolite using simulated body fluid.,” Colloids Surf. B. Biointerfaces, vol. 135, pp. 201–8, 2015.

 

(17) B. K. Billing, J. Singh, P. K. Agnihotri, and N. Singh, “Development of electrochemical sensor for selective recognition of PO43− ions using organic nanoparticles of dipodal receptor in aqueous medium,” Electrochim. Acta, vol. 182, pp. 1112–1117, 2015.

 

(18) B. Kaur, R. Srivastava, and B. Satpati, “Silver nanoparticle decorated polyaniline–zeolite nanocomposite material based non-enzymatic electrochemical sensor for nanomolar detection of lindane,” RSC Adv., vol. 5, no. 71, pp. 57657–57665, 2015.

 

(19) B. Ugale and C. M. Nagaraja, “Construction of 2D interwoven and 3D metal–organic frameworks (MOFs) of Cd( ii ): the effect of ancillary ligands on the structure and the catalytic performance for the Knoevenagel reaction,” RSC Adv., vol. 6, no. 34, pp. 28854–28864, 2016.

 

(20) B. Sarmah, R. Srivastava, P. Manjunathan, and G. V. Shanbhag, “Green and Sustainable Tandem Catalytic Approach for Fine-Chemicals Synthesis Using Octahedral MnO2 Molecular Sieve:Catalytic Activity versus Method of Catalyst Synthesis,” ACS Sustain. Chem. Eng., vol. 3, no. 11, pp. 2933–2943, 2015.

 

(21) B. Kaur, R. Srivastava, and B. Satpati, “Ultratrace detection of toxic heavy metal ions found in water bodies using hydroxyapatite supported nanocrystalline ZSM-5 modified electrodes,” New J. Chem.,vol. 39, no. 7, pp. 5137–5149, 2015.

 

(22) B. Kaur and R. Srivastava, “A polyaniline–zeolite nanocomposite material based acetylcholinesterase biosensor for the sensitive detection of acetylcholine and organophosphates,” New J. Chem., vol. 39, no. 9, pp. 6899–6906, 2015.

 

(23) C. M. Nagaraja, B. Ugale, and A. Chanthapally, “Construction of 2D interwoven and 3D interpenetrated metal-organic frameworks of Zn(ii) by varying N,N′-donor spacers,” CrystEngComm, vol. 16, no. 22, pp. 4805–4815, 2014.

 

(24) C. A. Huerta-Aguilar, T. Pandiyan, P. Raj, N. Singh, and R. Zanella, “Fluorescent organic nanoparticles (FONs) for the selective recognition of Zn2+: Applications to multi-vitamin formulations in aqueous medium,” Sensors Actuators, B Chem., vol. 223, pp. 59–67, 2016.

 

(25) D. Singh and C. M. Nagaraja, “Auxiliary Ligand-Assisted Structural Variation of Cd(II) Metal–Organic Frameworks Showing 2D → 3D Polycatenation and Interpenetration:  Synthesis, Structure, Luminescence Properties, and Selective Sensing of Trinitrophenol,” Cryst. Growth Des., vol. 15, no. 7, pp. 3356–3365, Jul. 2015.

 

(26) D. Chadar, S. S. Rao, S. P. Gejji, B. Ugale, C. M. Nagaraja, M. Nikalje, and S. Salunke-Gawali, “Regioselective synthesis of a vitamin K3 based dihydrobenzo phenazine derivative: its novel crystal structure and DFT studies,” RSC Adv., vol. 5, no. 93, pp. 76419–76423, 2015.

 

(27) G. S. Goindi, S. N. Chavan, D. Mandal, P. Sarkar, and A. D. Jayal, “Investigation of Ionic Liquids as Novel Metalworking Fluids during Minimum Quantity Lubrication Machining of a Plain Carbon Steel,” Procedia CIRP, vol. 26, pp. 341–345, 2015.

 

(28) G. Kaur, A. Singh, P. Venugopalan, N. Kaur, and N. Singh, “Selective recognition of lithium(I) ions using Biginelli based fluorescent organic nanoparticles in an aqueous medium,” RSC Adv., vol. 6, no. 3, pp. 1792–1799, 2016.

 

(29) H. Chowdhury, N. Chatterjee, and A. Goswami, “An Eco-Friendly Route to N-Arylindoles by Iron- Catalyzed [2+2+2] Cycloaddition of Diynes with (Indol-1-yl)alkynes,” European J. Org. Chem., pp. 7735–7742, 2015.

 

(30) H. Kaur, J. Singh, S. Chopra, and N. Kaur, “Calix[4]arene based dipodal receptor nanohybrids for selective determination of chloride ions in aqueous media,” Talanta, vol. 146, pp. 122–129, 2016.

 

(31) H. Sharma, N. Kaur, and N. Singh, “Sensing in aqueous medium: mechanism and its application in the field of molecular recognition,” Anal. Methods, 2015.

 

(32) H. Sharma, N. Kaur, N. Singh, and D. O. Jang, “Synergetic catalytic effect of ionic liquids and ZnO nanoparticles on the selective synthesis of 1,2-disubstituted benzimidazoles using a ball-milling technique,” Green Chem., vol. 17, no. 8, pp. 4263–4270, 2015.

 

(33) J. Singh, M. Yadav, A. Singh, and N. Singh, “Zinc metal complex as a sensor for simultaneous detection of fluoride and HSO 4 − ions,” Dalt. Trans., vol. 44, no. 28, pp. 12589–12597, 2015.

 

(34) J. G. Hernandez, A. R. Silva, P. Thangarasu, R. H. Najera, A. D. Moreno, M. T. O. Ledesma, J. Cruz- Borbolla, and N. Singh, “Theoretical and experimental studies of phenol oxidation by ruthenium complex with N,N,N-tris(benzimidazol-2yl-methyl)amine,” J. Mol. Model., vol. 21, no. 9, p. 224, 2015.

 

(35) J. Singh, C.A. Huerta-Aguilar, H. Singh, T. Pandiyan, N. Singh, “Voltammetric Simultaneous Determination of Cu2+, Cd2+ and Pb2+ in Full Aqueous Medium Using Organic Nanoparticles of Disulfide Based Receptor,” Electroanalysis, vol. 27, pp. 2544–2551, 2015.

 

(36) K. Tayade, B. Bondhopadhyay, K. Keshav, S. K. Sahoo, A. Basu, J. Singh, N. Singh, D. T. Nehete, and A. Kuwar, “A novel zinc( <scp>ii</scp> ) and hydrogen sulphate selective fluorescent ‘turn-on’ chemosensor based on isonicotinamide: INHIBIT type’s logic gate and application in cancer cell imaging,” Analyst, vol. 141, no. 5, pp. 1814–1821, 2016.

 

(37) K. Balwinder, R. Srivastava, and B. Satpati, “A Novel Nanocrystalline Titanosilicate- Acetylcholinesterase Electrochemical Biosensor for the Ultra Trace Detection of Toxic Organophosphate Pesticides,” ChemElectroChem, vol.2, pp. 1164-1173, 2015.

 

(38) M. Kumar, H. Singh, N. Singh, N. M. Chavan, S. Kumar, and S. V. Joshi, “Development of Erosion- Corrosion-Resistant Cold-Spray Nanostructured Ni-20Cr Coating for Coal-Fired Boiler Applications,” J. Therm. Spray Technol., vol. 24, no. 8, pp. 1441–1449, 2015.

 

(39) M. Sonawane, S. K. Sahoo, J. Singh, N. Singh, C. P. Sawant, and A. Kuwar, “A lawsone azo dyebased fluorescent chemosensor for Cu2+ and its application in drug analysis,” Inorganica Chim. Acta, vol. 438, pp. 37–41, 2015.

 

(40) M. Kumar, H. Singh, N. Singh, and R. S. Joshi, “Erosion-corrosion behavior of cold-spray nanostructured Ni-20Cr coatings in actual boiler environment,” Wear, vol. 332–333, pp. 1035–1043, 2015.

 

(41) M. Kaur and C. M. Nagaraja, “Template-free synthesis of ZnS nanocrystals with a new sulfur source and their photocatalytic study,” Mater. Lett., vol. 154, pp. 90–93, Sep. 2015.

 

(42) N. Kaur, J. Singh, P. Raj, N. Singh, H. Singh, S. K. Sharma, D. Y. Kim, and N. Kaur, “ZnO decorated with organic nanoparticles based sensor for the ratiometric selective determination of mercury ions,” New J. Chem., vol. 40, no. 2, pp. 1529–1534, 2016.

(43) N. Hussain and V. K. Bhardwaj, “The influence of different coordination environments on onedimensional Cu( <scp>ii</scp> ) coordination polymers for the photodegradation of organic dyes,” Dalt. Trans., pp. 7697–7707, 2016.

 

(44) N. Chatterjee and A. Goswami, “Metal and base free synthesis of primary amines via ipso amination of organo boronic acids mediated by [bis(trifluoroacetoxy)iodo]benzene (PIFA),” Org. Biomol. Chem., vol. 13, no. 29, pp. 7940–7945, 2015.

 

(45) N. Singh, B.K. Billing, J. Singh, P.K. Agnihotri Thiourea, “Based Dipodal Receptor Development for Electrochemical Detection of Br − Ion in an Aqueous Medium,” Electroanalysis, vol. 28, pp.718–723, 2016.

 

(46) N. Kaur, S.K. Sharma, B. Lee, S. Lee, D.Y. Kim, H. Sharma, N. Singh, “Synthesis of Imine-Bearing ZnO Nanoparticle Thin Films and Characterization of Their Structural, Morphological and Optical Properties,” Nanoscience and Nanotechnology, vol. 15, no. 10, pp. 8114-8119, 2015.

 

(47) P. Rani and R. Srivastava, “Nucleophilic addition of amines, alcohols, and thiophenol with epoxide/olefin using highly efficient zirconium metal organic framework heterogeneous catalyst,” RSC Adv., vol. 5, pp. 28270–28280, 2015.

 

(48) P. Banerjee, A. K. Pandey, "One Pot Synthesis of Oxazolidine Derivatives via [3+ 2]-Annulation Reaction of 1-Tosyl-2-phenyl/alkyl aziridines with Aryl Epoxides," Asian Journal of Organic Chemistry, vol. 5, pp. 360–366, 2016.

 

(49) P. Torawane, K. Tayade, S. Bothra, S. K. Sahoo, N. Singh, A. Borse, and A. Kuwar, “A highly selective and sensitive fluorescent ‘turn-on’ chemosensor for Al3+ based on C=N isomerisation mechanism with nanomolar detection,” Sensors Actuators, B Chem., vol. 222, pp. 562–566, 2016.

 

(50) R. Srivastava, B. Kaur, and B. Satpati, “A novel gold nanoparticles decorated nanocrystalline zeolite based electrochemical sensor for the nanomolar simultaneous detection of cysteine and glutathione,” RSC Adv., vol. 5, pp. 95028–95037, 2015.

 

(51) R. Dhiman and R. Chandel, “Compact models and computation of crosstalk for sub-threshold interconnect circuits,” Analog Integr. Circuits Signal Process., vol. 82, no. 3, pp. 637–652, 2015.

 

(52) R. Gutkowski, D. Schäfer, T. C. Nagaiah, JEY Heras, W. Busser, M. Muhler,“Efficient Deposition of Semiconductor Powders for Photoelectrocatalysis by Airbrush Spraying,” Electroanalysis, vol. 27,pp. 285-292, 2015.

 

(53) S. Patil, R. Patil, U. Fegade, B. Bondhopadhyay, U. Pete, S. K. Sahoo, N. Singh, A. Basu, R. Bendre,and A. Kuwar, “A novel phthalazine based highly selective chromogenic and fluorogenic chemosensor for Co(2+) in semi-aqueous medium: application in cancer cell imaging.,” Photochem.Photobiol. Sci., vol. 14, no. 2, pp. 439–43, 2015.

 

(54) S. S. Dhankhar, M. Kaur, and C. M. Nagaraja, “Green Synthesis of a Microporous, Partially Fluorinated Zn II Paddlewheel Metal-Organic Framework: H 2 /CO 2 Adsorption Behavior and Solid-State Conversion to a ZnO-C Nanocomposite,” Eur. J. Inorg. Chem., p. n/a–n/a, 2015.

 

(55) S. Sharma, J. Singh, N. Singh, and G. Hundal, “Spectroscopic and theoretical evaluation of solventassisted, cyanide selectivity of chromogenic sensors grounded on mesitylene platform and their biological applications,” Sensors Actuators B Chem., vol. 225, pp. 141–150, 2016.

 

(56) S. N. Chavan and D. Mandal, “Combined effect of ether and siloxane substituents on imidazolium ionic liquids,” RSC Adv., vol. 5, no. 80, pp. 64821–64831, 2015.

 

(57) S. N. Chavan, A. Tiwari, T. C. Nagaiah, and D. Mandal, “Ether and Siloxane Functionalized Ionic Liquids and their Mixtures as Electrolyte for Lithium-ion Batteries,” Phys. Chem. Chem. Phys., 2016.

 

(58) S. Chopra, J. Singh, H. Kaur, N. Singh, and N. Kaur, “Estimation of biogenic amines and bio thiols by metal complex of fluorescent organic nanoparticles acting as single receptor multi-analyte sensor in aqueous medium,” Sensors Actuators B Chem., vol. 220, pp. 295–301, 2015.

 

(59) S. Rajkumar, S. Antony Savarimuthu, R. Senthil Kumaran, C. M. Nagaraja, and T. Gandhi,“Expedient synthesis of new cinnoline diones by Ru-catalyzed regioselective unexpected deoxygenation-oxidative annulation of propargyl alcohols with phthalazinone and pyridazinones,” Chem. Commun., vol. 2, pp. 2–5, 2016.

 

(60) S. K. Sharma, N. Kaur, J. Singh, S. Sankar, S. S. Gaur, S. Lee, N. Singh, H. Singh, “Electrochemical Sensitive Determination of Nanomolar Guanine from ZnO Nanorods Coated on Platinum Electrode,” Electroanalysis, vol.27, pp. 2537–2543, 2015.

 

(61) T. Raj, B. Kaur Billing, N. Kaur, and N. Singh, “Design, synthesis and antimicrobial evaluation of dihydropyrimidinone based organic–inorganic nanohybrids,” RSC Adv., vol. 5, no. 58, pp. 46654–46661, 2015.

 

(62) V. K. Bhardwaj, “Potassium induced stitching of a flexible tripodal ligand into a bi-metallic twodimensional coordination polymer for photodegradation of organic dyes.,” Dalton Trans., vol. 44, no. 19, pp. 8801–4, 2015.

 

(63) U. Fegade, J. Bhosale, H. Sharma, N. Singh, R. Bendre, and A. Kuwar, “Fluorescence Chemosensor, for HSO4 − Ion Based on Pyrrole-Substituted Salicylamide Zn2+ Complex: Nanomolar Detection,” J. Fluoresc., vol. 25, no. 4, pp. 819–824, 2015.

 

Conference Proceedings

1. A. Tiwari and Tharamani C. Nagaiah, “Electrocatalytic Activity of Tungsten-oxide Nanoclusters Engrafted Mesoporous Nitrogen Rich Carbon in Dioxygen Reduction Reaction” at Australia-India Strategic Research Fund Research Meeting -2015 on Advanced Nanomaterials for Energy, Optoelectronics, and Biological Applications, Institute of Nano Science and Technology, Mohali, India, November, 25-27, 2015.

 

2. A. Joshi and Tharamani C. Nagaiah, “Simultaneous determination of ascorbic acid, dopamine and uric acid using mesoporous nitrogen containing carbon” at International Conference on Advances in Chemical Engineering, National Institute of Technology Karnataka, Surathkal, India, December 20- 22, 2015.

 

3. A. Tiwari and Tharamani C. Nagaiah, “Electrocatalytic borohydride oxidation by supported tungsten oxide nanoclusters towards direct borohydride fuel cells” at International Conference on Advances in Chemical Engineering, National Institute of Technology Karnataka, Surathkal, India, December 20-22, 2015.

 

4. Peeyush K. Sharma and Yashveer Singh, “Fabrication and Evaluation of hydrazone linkage-based in-situ forming pH Sensitive PEG hydrogel for controlled microbicide Release” at 15th International Conference of Controlled Release Society - Indian Chapter, Institute of Chemical Technology, Mumbai, India, February 19-20, 2016.

 

5. Peeyush K. Sharma and Yashveer Singh, “Fabrication and in vitro evaluation of in situ forming pHsensitive PEG-based hydrogels for microbicide delivey” at 3rd International Conference on Nanostructured Materials and Nanocomposites, Hindustan College of Science and Technology, Mathura, December 12-14, 2015.

 

6. Peeyush Sharma and Yashveer Singh, “In situ forming pH sensitive PEG based hydrogels for vaginal microbicide delivery” 1st CRICK Nanoscience Day, Institute of Nanoscience and Technology (INST), Mohali, July 21, 2015.

 

7. R. Kaur and T. J. Dhilip Kumar, “Ultracold Collisions of Rotational Quenching in the H+ + CO and H + CS+ Systems” at 18th CRSI National Symposium in Chemistry, Panjab University Chandigarh, February 5, 2016.

 

8. S. N. Chavan and D. Mandal, “Perfluoroether substituted imidazolium ionic liquids and their Applications” at Challenges in Organic Materials and Supramolecular Chemistry (ISACS 18), November 19-21, 2015, Indian Institute of Science, Bangalore, India.

 

9. S. Maji, D. Mandal, "Cavity modulation of meso-substituted calix[4]pyrrole for anion binding and metal complexation study," at 10th Mid Year Chemical Research Society of India (CRSI), Symposium in Chemistry – 2015, National Institute of Technology Trichy, Tamil Nadu on 23rd July 2015.

 

 

10. S. Kumar and T. J. Dhilip Kumar, “Theoretical Study of H2 Storage in Metal Functionalized Calix[4]arene System” at 18th CRSI National Symposium in Chemistry, Punjab University Chandigarh, February 5, 2016.